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https://apo.ansto.gov.au/dspace/handle/10238/3915| Title: | Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide |
| Authors: | Thorogood, GJ Zhang, Z Hester, JR Kennedy, BJ Ting, J Glover, CJ Johannessen, B |
| Keywords: | Cations Oxides Synchrotrons Neutron diffraction Vertebrae X-ray spectra |
| Issue Date: | 11-Nov-2011 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Thorogood, G.J., Zhang, Z.M., Hester, J.R., Kennedy, B.J., Ting, J., Glover, C.J., & Johannessen, B. (2011). Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide. Dalton Transactions, 40(41), 10924-10926. doi:10.1039/c1dt10954e |
| Abstract: | The structure of TcCo(2)O(4) has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc-O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent. The structure of TcCo(2)O(4) has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc-O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent.© 2011, Royal Society of Chemistry |
| Gov't Doc #: | 3833 |
| URI: | http://dx.doi.org/10.1039/c1dt10954e http://apo.ansto.gov.au/dspace/handle/10238/3915 |
| ISSN: | 1477-9226 |
| Appears in Collections: | Journal Articles |
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