Synthesis, structure and gas-phase reactivity of a silver hydride complex ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4

Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/6384

Title:	Synthesis, structure and gas-phase reactivity of a silver hydride complex ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4
Authors:	Zavras, A Khairallah, GN Connell, TU White, JM Edwards, AJ Donnelly, PS O'Hair, RAJ
Keywords:	Mass spectroscopy Ligands Catalysts Alkynes Gold compounds Crystallization
Issue Date:	5-Aug-2013
Publisher:	John Wiley and Sons
Citation:	Zavras, A., Khairallah, G. N., Connell, T. U., White, J. M., Edwards, A. J., Donnelly, P. S., & O'Hair, R. A. J. (2013). Synthesis, structure and gas-phase reactivity of a silver hydride complex Ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4. Angewandte Chemie-International Edition, 52(32), 8391-8394. doi:10.1002/anie.201302436
Abstract:	Mass spectrometry shows the way! MS analysis of silver salts treated with sodium borohydride in the presence of a bis(phosphino) ligand revealed the formation of novel silver hydride nanocluster cations instead of all silver nanocluster cations. This serendipitous discovery prompted the condensed-phase synthesis, isolation, and characterization of [Ag3{(Ph2P)2CH2}3(μ3-H)(μ3-Cl)]BF4⋅0.5 CHCl3. © 2013, Wiley‐Vch Verlag.
Gov't Doc #:	6234
URI:	http://dx.doi.org/10.1002/anie.201302436 http://apo.ansto.gov.au/dspace/handle/10238/6384
ISSN:	1433-7851
Appears in Collections:	Journal Articles

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