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Title: Synthesis, structure and gas-phase reactivity of a silver hydride complex ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4
Authors: Zavras, A
Khairallah, GN
Connell, TU
White, JM
Edwards, AJ
Donnelly, PS
O'Hair, RAJ
Keywords: Mass spectroscopy
Gold compounds
Issue Date: 5-Aug-2013
Publisher: John Wiley and Sons
Citation: Zavras, A., Khairallah, G. N., Connell, T. U., White, J. M., Edwards, A. J., Donnelly, P. S., & O'Hair, R. A. J. (2013). Synthesis, structure and gas-phase reactivity of a silver hydride complex Ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4. Angewandte Chemie-International Edition, 52(32), 8391-8394. doi:10.1002/anie.201302436
Abstract: Mass spectrometry shows the way! MS analysis of silver salts treated with sodium borohydride in the presence of a bis(phosphino) ligand revealed the formation of novel silver hydride nanocluster cations instead of all silver nanocluster cations. This serendipitous discovery prompted the condensed-phase synthesis, isolation, and characterization of [Ag3{(Ph2P)2CH2}3(μ3-H)(μ3-Cl)]BF4⋅0.5 CHCl3. © 2013, Wiley‐Vch Verlag.
Gov't Doc #: 6234
ISSN: 1433-7851
Appears in Collections:Journal Articles

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