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https://apo.ansto.gov.au/dspace/handle/10238/7482| Title: | Novel chemical synthesis and characterization of CeTi2O6 brannerite |
| Authors: | Kong, L Gregg, DJ Karatchevtseva, I Zhang, ZM Blackford, MG Middleburgh, SC Lumpkin, GR Triani, G |
| Keywords: | Cerium Titanates X-ray diffraction Thermal analysis Electron spectroscopy Brannerite |
| Issue Date: | 13-Jun-2014 |
| Publisher: | ACS Publications |
| Citation: | Kong, L., Gregg, D. J., Karatchevtseva, I., Zhang, Z., Blackford, M. G., Middleburgh, S. C., Lumpkin, G. R., & Triani, G. (2014). Novel chemical synthesis and characterization of CeTi2O6 brannerite. Inorganic Chemistry, 53(13), 6761-6768. doi:10.1021/ic500563j |
| Abstract: | Cerium titanate CeTi2O6 was prepared by a new soft chemistry route in aqueous solution. A suite of characterization techniques, including X-ray diffraction, thermal analysis, vibrational spectroscopy, and scanning and transmission electron spectroscopy, were employed to investigate the brannerite structure formation and its bulk properties. The synthesized powder formed the brannerite crystal structure upon calcination at temperatures as low as 800 °C. Samples sintered at 1350 °C possess a high level of crystallinity. X-ray absorption near-edge structure results indicate the presence of six-coordinated Ce4+ in the brannerite samples. © 2014, American Chemical Society. |
| Gov't Doc #: | 7069 |
| URI: | http://dx.doi.org/10.1021/ic500563j http://apo.ansto.gov.au/dspace/handle/10238/7482 |
| ISSN: | 1520-510X |
| Appears in Collections: | Journal Articles |
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